CHEMISTRY FORM FOUR TOPIC 4: POLLUTION
UNAWEZA JIPATIA NOTES ZETU KWA KUCHANGIA KIASI KIDOGO KABISA:PIGA SIMU:0787237719
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CHEMISTRY FORM FOUR TOPIC 4: POLLUTION
Concept of Pollution
- Terrestrial (land) pollution
- Aquatic (water) pollution
- Aerial (air) pollution
Terrestrial Pollution
- poor methods of irrigation which causes the leaching of cations down the soil surface;
- manure heaped on land, which may leach down the soil; and
- oil spillages that seep into the soil.

- Wastes dumped carelessly can endanger the health of man as well as other organisms. Broken glass, metal and other sharp objects may pierce one‟s skin and introduce disease germs into the body. Empty cans, glass and plastic containers are potential breeding grounds for mosquitoes which spread malaria and other diseases. Rotten organic matter may harbour many disease germs and they also produce noxious smell when they rot. The rotten wastes also attract flies which transmit a number of enteric diseases like dysentery, cholera, diarrhoea, etc.
- Land pollution causes chemical contamination to the ecosystem. This occurs when the chemicals in the waste matter poison the soil. Then plants growing on the poisoned soil, animals that eat these plants and even humans are all affected by these chemicals. This process is called biomagnifications and is a serious threat to the ecology. It can lead to the loss of some types of plants and animal life as well as create long-term health problems such as cancer and other deformities in humans. Radiation from nuclear wastes causes healthy problems such as cancers and other deformities.
- Piles of waste in urban areas keep growing due to increase in waste. When this waste is burned it produces a lot of smoke that leads to air pollution.
- Soil erosion (as a form of land pollution) leads to loss of land for agriculture, settlement, forest cover, fodder patches for grazing, etc.
- Land pollution leads to loss of ecosystem and hence directly or indirectly cause change in climatic patterns.
- Deforestation causes imbalance in the rain cycle. A disturbed rain cycle affects a lot of factors such as reduction in the green cover. Plants help absorb excess carbon dioxide from the air and release oxygen to the atmosphere. This process helps to balance the atmosphere. Without vegetation cover, excessive accumulation of carbon dioxide in the atmosphere causesconcerns like global warming, the greenhouse effect, irregular rainfall, and floods among other imbalances.
- Land pollution damages terrestrial life, especially plants. This greatly affects wildlife and other animal species which are forced to move further away and adapt to new regions or die trying to adjust.
- Heaps of different wastes from mining activities make the environment unsightly and ugly.
- Terrestrial pollution is a big problem in urban areas where waste production outweighs waste disposal. In such areas you find poor and blocked sewage system, effluent from domestic toilets flowing on the streets and roads, and dirty water carelessly poured on the ground. This makes life in urban areas uncomfortable and a mere nuisance.

- biopolymers such as those used in making surgical sutures;
- photodegradable plastics, which break down upon exposure to light: and
- soluble plastics which can be broken down by water
Proper disposal of wastes

Reducing the use of agrochemicals
Making and enacting environmental laws and policies
- discharge and treatment of sewage;
- disposal of lethal nuclear wastes;
- use of agrochemicals in agricultural production;
- use of plastic and related materials;
- disposal of toxic chemicals and solid wastes from industries; and
- careless littering of the environment by irresponsible people.
Creating public awareness
Aquatic Pollution
Pesticides
Fertilizer (nutrient pollution)
Oil spills
Mining
- The mining process exposes heavy metals and sulphur compounds that were previously locked deep in the earth. Rain water leaches these compounds out of the exposed earth, resulting in “acid mine drainage” and heavy metal pollution that can continue long after the mining operations have practically ceased.
- The action of rain water on piles of mining waste (tailings) transfers pollution to freshwater supplies.
- In gold mining, cyanide is intentionally poured on piles of mined rock (a leach heap) to chemically extract the gold from the ore. Some of the cyanide ultimately finds its way into nearby water.
- Huge pools of mining waste slurry (semi-liquid mixture) are often stored behind containment dams. If a dam leaks or bursts, water pollution is likely to take place.
- Mining companies in developing countries sometimes dump mining waste directly into rivers or other water bodies as a method of disposal.
Sediment
Industrial processes
Sewage
Marine debris (marine litter)

Air pollution
Heat
Noise
The Hazards which are Caused by Water Pollution
Waterborne diseases
Nutrient pollution
Chemical contamination
Pesticides
Oil spills
Mercury
Young children and unborn babies are at a higher risk because their body systems are still developing. Exposure to mercury in unborn babies can cause neurological problems such as slower reflexes, learning deficit, delayed or incomplete mental development, autism, and brain damage.
Mercury can also cause serious nervous system problems in adults. These problems include Parkinson‟s disease, multiple sclerosis, and Alzheimer‟s disease. It can also cause heart disease and damage to the brain.
Industrial chemicals

Mining
Acid Mine Drainage (AMD):

Spills and leaks:

Marine debris

Thermal pollution
Noise pollution
Ways of Preventing Water Pollution
Reducing nutrient and pesticide pollution
Treating sewage and industrial wastes

Stopping deforestation
Controlling coastal development
Reducing pollution from oil spills
Enforcing the regulations and rules that govern maintenance and inspection of commercial ships and other marine vessels that leak oil and fuel into the water.
Cleaning oil spills as promptly as they occur.
Converting oil tankers into double-hull ships. A double-hull ship has two complete layers of watertight hull surface. The178outer layer forms the normal hull of the ship. A second inner hull forms a protective barrier to sea water in case the outer hull is damaged and leaks.
Educating the public how to keep oil out of the environment.
Controlling production of greenhouse gases
Reducing mercury emissions
Cleaning up existing and abandoned mines
Mining companies should clean up abandoned mines which continue to release pollutants to the environment.
New mines should not be established in areas where they are likely to cause water pollution problems.
Mining practices which cause water pollution should be banned.
Cleaning up chemical pollution
Aerial Pollution

Carbon dioxide
Carbon monoxide
Ground level ozone (smog)

Nitrogen oxides


Sulphur compounds
Particulate matter (PM)
Lead
Chlorofluorocarbons (CFCs)
CHEMISTRY FORM FOUR TOPIC 4: POLLUTION
Health problems
Global warming
Depletion of the ozone layer
Acid rain
Eutrophication

Effect on wildlife
Different Methods of Preventing Air Pollution

Using energy-efficient devices

Using public transport

Reducing pollution from fossil fuels
the exhaust of new cars are fitted with catalytic converters in which harmful gases are converted to harmless ones; manufacturers are looking at ways to make car engines more efficient so that they can use less petrol, and other alternative fuels; coal is turned into smokeless fuel for use in homes; and scientists are looking at ways to make homes and factories more energy efficient, so that we can burn less fuel, not more.
Use of air pollution control devices
Law enforcement
Eliminate or substitute hazardous chemicals
using water-based paints or glues instead of those that are organic solvent based (figure 4.17);
using water-detergent solutions instead of solvents; and
using trichloromethane as a degreasing agent instead of trichloroethylene.

Use of protective gears

Ventilation
Environmental Conservation
Sustenance of life
Protection of animal and plant species

Economic value
Future generations
Beauty/austhecy

Setting up organizations and institutions
Legislation
Education
Research
alternative sources of energy;
methods of preventing and controlling pollution;
sustainable use of natural resources;
recycling and reuse of material;
environmental impact assessment.
Pollution prevention and control
International agreement
Personal involvement
- Plant more trees at home and farm fields, school and village forest. Do not cut down tress indiscrimately because doing so leaves the soil bare and vulnerable to soil erosion.
- Always dump litter in areas designated for waste disposal and in litter bins. Do not just throw dirt anywhere and carelessly.
- Do not start fires near forests. Farmers should not prepare their farm fields by burning the vegetation because the fire can spread and destroy trees and nearby forests. Fire also kills important soil microorganisms, thus curtailing soil fertility and productivity.
- Do not harm domestic and wild animals by any means. Be kind to animals and treat them humbly.
- Convey environmental conservation education to all people. Let them know the importance of conserving and living in a clean environment.
- Participate in environmental conservation programmes and tasks. These include World environment Day (June 5, every year) and clear-up exercises in the local area or town.
Global Warming
The Global Warming in Terms of ‘Green House’ Effect
How the Major “Greenhouse” Gases are Produced
Carbon dioxide
Deforestation

Methane
Nitrous oxide (dinitrogen oxide, N2O)
Chlorofluorocarbons (CFCs)
Climatic Conditions caused by Global Warming
Increase in average temperatures
Extreme weather events

higher or lower agricultural yields;
melting of arctic ice and snowcaps. This causes landslides, flash floods and glacial lake overflow;
extinction of some animal and plant species; and increase in the range of disease vectors, that is, organisms that cause diseases.
Change in world’s climate patterns
Rise in sea levels
Ocean acidification
Effects on plants and animals
Effects on humans
Ways of Preventing Global Warming
- Conserving the energy so as to reduce the use of fossil fuels which produce greenhouse gases. Such measures can be taken by using public transport to reduce the number of motor vehicles on the road and using cars that consume a little fuel.
- Minimize the use of deodorants, as they contain CFCs (chlorofluorocarbons) that contributes to the ozone depletion, which in turn gives rise to most destructive effects.
- Planting more trees (afforestation) and avoiding cutting down trees (deforestation) carelessly. This is because forests play an important role in absorbing carbon dioxide, thus reducing the amount of carbon dioxide in the atmosphere.
- Encourage the use of renewable sources of energy like wind, biomass, solar, and geothermal energy. The use of solar power and biomass should be installed widely. But there are a few obstacles that are delaying the use of these technologies.
- Raise awareness! Educate people about global warming and its disastrous effects. Share various solutions to stop global warming. Make sure you take initiatives to help conserve the environment and encourage others to do the same.
- Countries, including Tanzania, have ratified the international agreements aiming at minimizing the emission of greenhouse gases. One of those agreements is the Kyoto Protocol.
- 1. CCl3F → •CCl2F + •Cl2.
- •Cl + O3 → •ClO + O23.
- •ClO + O3 → •Cl + 2O2
Chemical Substances which Destroy the Ozone Layer
The most widely used ODS, accounting for over 80% of total stratospheric ozone depletion.Used as coolants in refrigerators, freezers and air conditioners in buildings and cars manufactured before 1995.Found in industrial solvents, dry-cleaning agents and hospital sterilizers.Also used in foam products such as soft-foam padding (e.g. cushions and mattresses) and rigid foam (e.g. home insulation)
Used mainly in industry as a solvent in many products and for metal cleaning.
Used in solvents and some fire extinguishers.
HCFCs have become major, “transitional” substitutes for CFCs. They are much less harmful to stratospheric ozone than CFCs are. However, HCFCs still cause some ozone destruction and are potent greenhouse gases.
Possible effects of ozone depletion
Impact on humans
Effects on amphibians
Hinders growth and development in larvae.
Changes behaviour and habits.
Causes deformities in some species.
Decreases immunity: Some species have become more vulnerable to diseases and death.
Retinal damage and blindness in some species.
Effects on marine ecosystems
Suggest methods of protecting the ozone layer
refrigerants in refrigerator and air conditioning units;
propellants in aerosol cans;
solvents and blowing agents for insulation foams;
cleaners in electronic industry;
fire extinguisher chemicals.
Eliminating the use of CFCs will prevent the depletion of ozone layer. New refrigerants have been developed and new aerosols use other propellants such as methane in place of CFCs.
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