FORM THREE PHYSICS STUDY NOTES TOPIC TOPIC 9: THERMAL CURRENT ELECTRICITY
FORM THREE PHYSICS STUDY NOTES TOPIC TOPIC 9: THERMAL CURRENT ELECTRICITY

- At cathode: The zinc plate dissolves in the sulphuric acid solution and liberates electrons into the external circuit. The metal discus had to be of different material Volta used copper and zinc discs sand witched by cloth soaked in salt water. The combined device was called a voltaic pile. Volta also obtained the same effects by using copper and zinc plates dipped in dilute sulphunic acid. Volta called these devices, arranged in series. The “ Crown of cups” zn – 2e – Zn 2+ The 2n 2+ ions go into solution.
- At anode: Positively charged hydrogen lons (H+) are attracted towards the negatively charged copper plate2H + + 2e —– H2.The chemical reaction in the cell creates a potential different between plates, causing electrons to flow when the two plates are joined with a wire. The electrons flow is maintained by the chemical change that occurs when the zinc dissolves in the sulphuric acid. Since simple cell, which is able to adrive an electric current through a circuit, is said to be a source of electromotive force (e.m.f)
- Polarisation
- Local Action
- Polarisation can be minimised by using suitable oxidising agents, called depolarisers, to remove the hydrogen. An example of depolarisers for hydrogen is potassium dichromate. The dichromate oxidizes the hydrogen to form water.
- Lead Acid accumulators
- Nickel – Cadmium accumulators
- Alkaline and chloride accumulators
Is the process of using charges stored in the lead – Acid Accumulator.
When the accumulator is discharged after long use both plate become coated with lead sulphate.
The relative density (R.D) of Acid also become less and the P.d of cell falls.
Recharging will restore the plate of lead (iv) oxide and lead, and the relative density of acid will rise to 1.25
The accumulator must not allowed to discharge below the stated values of p.d and Relative density, or it will not be possible to recover it on recharging.
The capacity of an accumulator is the amount of current in amperes that the cell can send thought a circuit is measured in ampere – Hour (Ah)
The charging rate an Accumulator is a current in amperes, numerically equal to one – tenth (1/10) of the capacity required in Recharging.
Lead-acid accumulators have high e.m.f (2v per cell) and allow internal Resistance.
Accumulators are best cared for by a regular check of the level of the sulphuric acid.
Any loss due to evaporation must be replenished with distilled water only.
No acid should be added unless there has been same spillage from the cell.
Accumulators must be recharged regularly using the charging current recommended by the manufactures.
They should not left in discharged condition for a long time.
When not in use they should be recharged at least once every month.
An accumulator should never be short-circuited.
Shorting the cell may cause swelling and buckling of the plates due to excessive heat developed in the cell, leading to permanent damage (A cell in this condition is said to be sulphated).
- Electric cells are very useful when no mains supply of electricity is available or when connecting to a main supply of electricity would be inconvenient.
- Portable radios, torches, calculators and watches are example of devices that use primary cells.
- It is possible to buy rechargeable batteries for these devices.These are secondary cells to start the engine and to run all the electrical circuits.
- This cell is recharged by the alternator when the car is in use.
No comments: